TIME-RESOLVED FLUORESCENCE STUDY OF TRIPLE EXCIPLEX FORMED IN THE SYSTEM OF POLY(2-VINYL) NAPHTHALENE AND TEREPHTHALIC DIMETHYLESTER

作     者：章立民 张月平 陈凯 

作者机构：Institute of Chemistry Academia Sinica Beijing 100080 PRC 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：1991年第34卷第1期

页      面：26-34页

核心收录：

学科分类：07[理学] 0703[理学-化学] 

主　　题：triple exciplex exciplex poly(2-vinyl) naphthalene 2-vinylnaphthalene time-resolved fluorescence 

摘      要：An intramolecular excimer of poly(2- vinyl) naphthalene was formed by non-adjacent chromophores interaction, then a triple exciplex was formed by interaction with the acceptor molecule further in dilute solution. The lifetime of the intramolecular excimer of poly(2- vinyl) naphthalene, τ_2 = 18.83 ns and the rate constant for the triple exciplex formation, k_7 = 4. 18× 10~9 (mol/L)^(-1)s^(-1), under diffusion-control were measured. An excimer or an exciplex could be an intermediate of the triple exciplex formation. A theoretical model of the triple exciplex formation is proposed.