FORMATION OF MESOGLOBULES BY POLY(N,N-DIETHYLACRYLAMIDE)CHAINS IN DILUTE SOLUTIONS

作     者：张广照 

作者机构：Department of Chemical PhysicsUniversity of Science and Technology of China 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2009年第27卷第4期

页      面：561-567页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 0817[工学-化学工程与技术] 08[工学] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(NNSFC)(Nos.20574065 and 50333050) the Hong Kong Special Administration Region(HKSAR) Earmarked Project(CUHK4036/05P,2160269) 

主　　题：Mesoglobule Light scattering Microcalorimetry 

摘      要：The association of poly(N,N-diethylacrylamide)(PDEA) chains has been investigated by a combination of static and dynamic laser light scattering(LLS).Unlike poly(N-isopropylacrylamide)(PNIPAM),PDEA chains can not form the C=O…H-N hydrogen *** results demonstrate that a limited number of PDEA chains collapse and associate into metastable globules in dilute *** heating rate has great effect on the mesoglobule *** formation of such mesoglobules is attributed to the competition between intra...