A　New　Approach　for　Stabilizing　Organouranium　Dichloride：　Synthesis　and　X－ray　Structure　of　（MeOCH₂CH₂C₅H₄）₂UCl₂

作     者：Deng, DL Zhang, XF Qian, CT Sun, J Zheng, PJ Chen, J 

作者机构：CHINESE ACAD SCISHANGHAI INST ORGAN CHEMORGANOMET CHEM LABSHANGHAI 200032PEOPLES R CHINA FUDAN UNIVCTR ANAL & MEASUREMENTSHANGHAI 200433PEOPLES R CHINA 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：1996年第7卷第12期

页      面：1143-1144页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：CH Stabilizing Approach 

摘      要：s: CPUCI2 (CP = MeOCH2CH2C5H4) complex 1 has been synthesized by the reaction of UCl4 with Cp Na in tetrahydrofuran. A single-crystal X-ray study shows that the uranium compound is a mononuclear complex with uranium in a pseudo-hexahedral co-ordination geometry if the cyclopentadienyl ring is regarded as occupying a single polyhedral vertex.