Micro-galvanic corrosion behaviour of Mg-(7,9)Al-1Fe-xNd alloys
Mg-(7,9)Al-1Fe-xNd合金的微电偶腐蚀行为作者机构:School of Advanced ManufacturingNanchang UniversityNanchang 330031China Institute for Advanced StudyNanchang UniversityNanchang 330031China
出 版 物:《Transactions of Nonferrous Metals Society of China》 (中国有色金属学报(英文版))
年 卷 期:2024年第34卷第9期
页 面:2828-2848页
核心收录:
学科分类:080503[工学-材料加工工程] 08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)]
基 金:financial support from the National Natural Science Foundation of China(No.51961026)
主 题:magnesium alloy scanning Kelvin probe force microscope micro-galvanic corrosion in situ observation atomic force microscopy
摘 要:The localized micro-galvanic corrosion process and the kinetic information of Mg-(7,9)Al-1Fe-x Nd alloys were investigated by in situ observation under electrochemical control and in situ atomic force microscopy(AFM)in an electrolyte *** results revealed that the formation of the Nd-rich phase in alloys resulted in a decrease in the Volta potential difference from~400 m V(AlFe3/α-Mg)to~220 mV(Nd-rich/α-Mg),reducing the corrosion products around the cathodic phase and corrosion current density of the microscale *** addition of Nd significantly improved the corrosion resistance,mainly due to the suppression of the micro-galvanic corrosion between the second phases and ***,the corrosion mechanism of Mg-(7,9)Al-1Fe-x Nd alloys was discussed based on in situ observations and electrochemical results.