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Photo-induced Electron Transfer Between Hypocrellins and BNAH

Photo-induced Electron Transfer Between Hypocrellins and BNAH

作     者:安静仪 蒋丽金 

作者机构:Institute of Photographic Chemistry Academia Sinica Beijing 100101 PRC 

出 版 物:《Chinese Science Bulletin》 (科学通报(英文版))

年 卷 期:1993年第38卷第14期

页      面:1171-1176页

核心收录:

学科分类:07[理学] 08[工学] 

基  金:Project supported by the National Natural Science Foundation of China 

主  题:hypocrellins hypocrellin semiquinone radicals electron transfer BNAH. 

摘      要:1 Introduction Much research work has been done on the mechanism of photo-induced reduction of quinone dyes by electron donors with visible light. Two ways to obtain the net two-electron reduction product QH^- bave been proposed. One is the direct two-electron transfer (electron-proton-electron transfer) within the complex and the other is the disproportionatioh of the semiquinone radical QH·formed by one-electron transfer.

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