Recent progress in sulfonyl fluoride synthesis via the radical sulfur dioxide insertion and fluorination strategy
作者机构：School of Chemical and Environmental Engineering Shanghai Institute of Technology Shanghai-Sanming Engineering Research Center of Green Fluoropharmaceutical Technology Key Laboratory of Fluorine and Nitrogen Chemistry and Advanced Materials Shanghai Institute of Organic ChemistryUniversity of Chinese Academy of Sciences Chinese Academy of Sciences
出 版 物：《Science China Chemistry》 (中国科学:化学(英文版))
年 卷 期：2024年
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金：support from the National Natural Science Foundation of China (No. 21871283) the project of Science and Technology Commission of Shanghai Municipality in China (No. 21010503800) Shanghai Engineering Research Center of Green Fluoropharmaceutical Technology the Science Research Foundation of Shanghai Institute of Technology
摘 要：Sulfonyl fluoride compounds, as the key components for sulfur(VI) fluoride exchange(SuFEx) reaction, are characterized by their high chemical stability yet can be selectively activated under specific conditions to enable efficient chemical bonding and connections. This unique capability has garnered significant interest across various domains. Many strategies have been developed for the synthesis of sulfonyl fluoride compounds. This review focuses on the latest advancements in synthesizing these compounds using the radical sulfur dioxide insertion and fluorination(RSIF) strategy, underscoring the versatility and efficacy of the RSIF strategy in constructing sulfonyl fluoride compounds.
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