Progress of photocatalytic CO_(2)reduction toward multi-carbon products

作     者：Jiaojiao Fang Chengyang Zhu Huiling Hu Jiaqi Li Licheng Li Haiyan Zhu Junjie Mao 

作者机构：Key Laboratory of Functional Molecular SolidsMinistry of EducationCollege of Chemistry and Materials ScienceAnhui Normal UniversityWuhu 241002China 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2024年第67卷第12期

页      面：3994-4013页

核心收录：

学科分类：0202[经济学-应用经济学] 02[经济学] 020205[经济学-产业经济学] 

基　　金：supported by the National Natural Science Foundation of China(22302002,22375006) the University Science Research Project of Anhui Province(2022AH050182,2022AH020020) 

主　　题：CO_(2)reduction photocatalysis multi-carbon products C-C coupling active sites 

摘      要：The photocatalytic CO_(2)reduction reaction(CO_(2)RR)represents a promising solution to alleviate environmental and energy issues stemming from CO_(2)emissions while simultaneously enabling the production of high-value multi-carbon ***,the efficient generation of multi-carbon products remains challenging due to high kinetic barriers,sluggish C–C coupling processes,and intricate reaction *** review provides a comprehensive overview of the latest advancements in synthesizing C_(2+)products through CO_(2)photoreduction,highlighting the crucial role of active site design and the C–C coupling ***,we emphasize the correlation between the structure of active sites and the key intermediates of C–C coupling,which is fundamental for achieving deep photoconversion of CO_(2).Finally,we offer a glimpse into future challenges and prospects,outlining potential directions for the development of CO_(2)-to-multicarbon photoconversion,aiming to contribute novel insights to this exciting field.