Research on Inorganic Anion Recognition of Calix[4]pyrroles and Dipyrrylmethanes by Capillary Zone Electrophoresis
Research on Inorganic Anion Recognition of Calixpyrroles and Dipyrrylmethanes by Capillary Zone Electrophoresis作者机构：Key Laboratory for Natural Medicine of Gansu Province Lanzhou Institute of Chemical Physics Graduate School of the Chinese Academy of Sciences Lanzhou Gansu 730000 China
出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)
年 卷 期：2005年第23卷第11期
页 面：1515-1518页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金：Project supported by the National Natural Science Foundation of China (No. 20275041)
主 题：calixpyrrole dipyrrylmethane anion recognition capillary electrophoresis inorganic anion
摘 要：Capillary electrophoresis （CE） can separate charged and neutral substances with high speed and efficiency. In this paper, utilizing meso-octamethylcalix[4]pyrrole, meso-tetraspirocyclohexylcalJx[4]pyrrole, bimethyl bi（2-pyrryl）- methane and 1,1-bi（2-pyrryl）cyclohexane as additives in capillary zone electrophoresis （CZE） electrolyte, their recognition ability to inorganic anions was discussed. The dipyrrylmethanes have better recognition ability than others. Their effects on separation of seven normal inorganic anions by CZE were studied.
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