Cyanide-bridged WⅤMnⅢ single-chain magnet based on an octacoordinate [W(CN)6(phen)]- anion

作     者：LEE JinWuk LIM KwangSoo YOON JungHee RYU DaeWon KOO BongHo KOH EuiKwan HONG ChangSeop 

作者机构：Department of Chemistry Research Institute for Natural Sciences Korea University Seoul 136-713 Korea Nano-Bio System Research Team Korea Basic Science Institute Seoul 136-713 Korea 

出 版 物：《中国科学:化学》 (Scientia Sinica(Chimica))

年 卷 期：2012年第42卷第6期

页      面：916-917页

核心收录：

学科分类：07[理学] 070203[理学-原子与分子物理] 0702[理学-物理学] 

主　　题：tungsten manganese cyanide crystal structure single-chain magnet 

摘      要：Reaction of unique [W(CN)6(phen)]- with a magnetically anisotropic Mn Schiff base yielded a WⅤ(5d)-MnⅢ(3d) bimetallic compound with a linear chain structure. The magnetic properties of the chain complex feature a ferrimagnetic behavior as well as slow magnetic relaxation typical for a single-chain magnet.