Synthesis of Fulleropyrrolidines under Microwave Irradiation
Synthesis of Fulleropyrrolidines under Microwave Irradiation作者机构：Department of Chemistry South China Normal University Guangzhou 510631 Department of Chemistry South China Normal University Guangzhou 510631 Department of Chemistry South China Normal University Guangzhou 510631 Department of Chemistry South China Normal University Guangzhou 510631
出 版 物：《有机化学》 (Chinese Journal of Organic Chemistry)
年 卷 期：2004年第24卷第z1期
页 面：105-页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金：Project supported by the National Natural Science Foundation of China (No. 20231020)
主 题：microwave irradiation photoinduced electron transfer calculation method organic reactions determination of electron donor
摘 要： In recent years, considerable efforts have been devoted to the development of systems in which C60 is covalently linked to an electron donor.[1] Studies[2] on intermolecular photoinduced electron transfer between C60 and triphenyl amine show that triphenyl amine is a good donor. It is envisaged that the use of donor segments consisting of either pyrrole/aniline may extend the lifetime of charge-separated state.[3] Since Gedye[4] demonstrated that many organic reactions can be conducted rapidly under microwave irradiation, here we have successfully synthesized five new fulleropyrrolidines containing triphenyl amine or thiophene dyads under microwave irradiation, which are different from traditional heating. The determination of structures of these fulleropyrrolidines is in progress. On the other hand, we have studied the geometry, electronic structures and frontier orbitals of these N-methyl-pyrrolo[3,4]C60 derivatives by using AM1semiempirical quantum calculation method. The results indicate that there exists strong intramolecular electron transfer in them.……
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