Analysis of Cadmium in Water Extracts from Contaminated Soils with High Arsenic and Iron Concentration Levels
Analysis of Cadmium in Water Extracts from Contaminated Soils with High Arsenic and Iron Concentration Levels作者机构：Groupe ISA Equipe Sols et Environnement Laboratoire Gdnie Civil et geo-Environnement （LGCgE） Lille Nord de France EA 4515 48 Boulevard Vauban Lille Cedex 59046 France
出 版 物：《Journal of Environmental Science and Engineering》 (环境科学与工程（英文版）)
年 卷 期：2011年第5卷第3期
页 面：271-280页
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 09[农学] 070302[理学-分析化学] 0901[农学-作物学] 0703[理学-化学]
主 题：ETAAS cadmium arsenic iron interference.
摘 要：Cadmium （Cd） concentrations in the water extracts of ten contaminated soils by arsenic （As） with various iron （Fe） contents were measured using inductively coupled plasma atomic emission spectrometry （ICP-AES） and electrothermal atomic absorption spectrometry （ETAAS）, Due to the potential spectral interferences of As and Fe in the quantification of Cd, two methods were used for the background compensation. The first method was based on the use of a deuterium lamp （BGCD2 mode）. The second one required a Cd hollow cathode lamp pulsated with a current for which the intensity varies in the course of time （BGCSR mode）. The results showed that the choices of the analytical technique and the method used for the background compensation depend on the Cd, As and Fe concentrations in the solution and the concentration ratios As/Cd or/and Fe/Cd. In comparison with the ICP-AES and the ETAAS in combination with the BGCD2 mode, it was shown that the high-speed self-reversal method （HSSR） was a more appropriate method to correct As and Fe spectral interferences during the Cd measurements. On the other hand, depending on the Cd concentration, it was established that no significant Fe interference occurred during the Cd determination even if Fe concentration was 50 mg/L, reflecting the efficiency of the HSSR method to overcome the Fe interferences in the determination of Cd concentration by ETAAS without any matrix modifier in water extracts.
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