Tourmalinization at the Darasun goldfield,Eastern Transbaikalia:Compositional,fluid inclusion and isotopic constraints

作     者：Vsevolod Prokofiev Ivan Baksheev Lidiya Zorina Boris Belyatsky Vladimir Ustinov Nadezhda Krivitskaya 

作者机构：Institute of Geology of Ore Deposits PetrographyMineralogy & GeochemistryRussian Academy of SciencesMoscowRussia Lomonosov Moscow State UniversityMoscowRussia Lomonosov Moscow State University MoscowRussia Vinogradov Institute of Geochemistry IrkutskRussia Institute of Precambrian Geology and Geochronology RASSaint-PetersburgRussia Vernadsky Institute of Geochemistry and Analytical Chemistry RASMoscowRussia 

出 版 物：《Geoscience Frontiers》 (地学前缘（英文版）)

年 卷 期：2012年第3卷第1期

页      面：59-71页

核心收录：

学科分类：070902[理学-地球化学] 0709[理学-地质学] 07[理学] 0708[理学-地球物理学] 0704[理学-天文学] 

基　　金：carried out within the framework of the UNESCOIGCP project 540"Gold-bearing hydrothermal fluids of orogenic deposits"and the Russian Foundation for Basic Research(projects 09-05-00697 and 11-05-1207ofi-m) 

主　　题：Tourmaline composition Fluid inclusions Oxygen isotopes Gold deposits Transbaikalia Russia 

摘      要：Zoned tourmaline （schorl-dravite） in the matrix of hydrothermal explosive breccia and ore veins in gold deposits, Chita region, Eastern Transbaikalia, Russia, are associated with Na- and K-rich porphyry-type subvolcanic intrusives. 61So values of tourmaline from three gold deposits （Darasun, Talatui, Teremkinskoye） are ＋8.3%, ＋7.6%, and --6.0% and calculated 6180 values of fluids respon- sible for the tourmalinization are ＋7.3%, ＋7.7%, and ＋4.2%, respectively. These data imply an igneous fluid source, except at the Teremkin deposit where mixing with meteoric water is indicated. Wide ranges of Fe3＋/Fetot and the presence of vacancies characterize the Darasun deposit tourmaline indicating wide ranges off（O2） and pH of mineralizing fluids. Initial stage tourmalines from the gold deposits of the Darasun ore district are dravite or high mg schorl. Second stage tourmaline is characterized by oscillatory zoning but with Fe generally increasing towards crystal rims indicating decreasing temperature. Third stage tourmaline formed unzoned crystals with XMg （mole fraction of Mg） close to that of the first stage tourmaline, due to a close association with pyrite and arsenopyrite. From Fe^3＋/Fetot values, chemical composition and crystallization temperatures, logf（O2） of mineralizing fluids ranged from ca. -25 to 20, much higher than for the gold-bearing beresite-listvenite association, indicating that tourmalinization was not related to gold mineralization.