Synthesis of binaphthyl bridged chiral bis-corrole

作     者：Ping Lian Hai Yang Liu Lan Ying Liu Lei Shi Huan Feng Jiang Chi Kwong Chang 

作者机构：Department of Chemistry and Life Sicence Gannan Normal University Ganzhou 341000 China Department of Chemistry South China University of Technology Guangzhou 510641 China Department of Chemistry The Hong Kong University of Science and Technology Hong Kong China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2009年第20卷第1期

页      面：21-24页

核心收录：

学科分类：1007[医学-药学(可授医学、理学学位)] 100705[医学-微生物与生化药学] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 10[医学] 

基　　金：supported by Natural Science Foundation of China(Nos.20771039 and 20572027) Research GrantCouncil of Hong Kong 

主　　题：Chiral bis-corrole Synthesis ICD 

摘      要：Chiral bis-corrole 1 and 2 were prepared by reaction of （s）-2,2′-bis（bromomethyl）-1, 1′-binaphthyl and 10-（4-hydroxylphenyl）- 5,15-bis（pentafluorophenyl）corrole or 10-（3-hydroxylphenyl）-5,15-bis（pentafluorophenyl）corrole in DMF at 60 ℃ in the presence of anhydrous K2CO3 with an isolated yield -8%. Both 1 and 2 exhibit unsymmetrical induced circular dichroism （ICD） in the soret band with positive exciton chirality.