ESTIMATION OF REACTIVITY RATIOS OF METHYL ACRYLATE WITH N-ARYLMETHACRYL-AMIDE COPOLYMERS BY ~1H NMR METHOD
ESTIMATION OF REACTIVITY RATIOS OF METHYL ACRYLATE WITH N-ARYLMETHACRYL-AMIDE COPOLYMERS BY ~1H NMR METHOD作者机构:Peking Univ China
出 版 物:《Chinese Journal of Polymer Science》 (高分子科学(英文版))
年 卷 期:1990年第8卷第1期
页 面:10-16页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学]
主 题:Reactivity Ratios Copolymerization Methyl Acrylate N-Arylmethacrylamide ~1H-NMR Method.
摘 要:The copolymerizations of methyl acrylate (MA) with different N- arylmethacrylamide (N-ArMA) were carried out in benzene solution by free radical initiation. The compositions of the copolymers were deter mined by;H NMR method. The monomer reactivity ratios were calculated by the Fineman-Ross (F-R) method. The reactivity ratios and the activity of various N-ArMA with MA were investigated.