Stereochemical Effects in Mass Spectrometry ( Ⅶ )——Negative Ion Fast Atom Bombardment Mass Spectro-metry of Saccharides with Areneboronic Acids as Reagents

作     者：YANG Hou-jun (Department of Chemistry, Tsinghua University, Beijing, 100084)CHEN Yao-zu (Department of Chemistry, Lanzhou University, Lanzhou, 730000)ZHAO Fan-zhi, LI Hai-quan, ZHAI Jian-jun and CHEN Nen-yu (Instrumental Analysis & Research Center, Lanzhou University, Lanzhou, 730000) 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：1992年第8卷第3期

页      面：231-238页

核心收录：

学科分类：07[理学] 0703[理学-化学] 

基　　金：Supported by the National Natural Science Foundation of China 

主　　题：Reaction mass spectrometry Stereochemical effect Saccharides 

摘      要：1-Naphthylboronic acid and 2, 4-dimethylphenylboronic acid can react stereospecif-ically with hydroxy groups of saccharides on the probe tip of a fast atom bombardment mass spectrometer to form characteristic negatively-charged boronate ions. On the basis of the relative abundances of these characteristic ions, the epimers of mono- and di-saccharides may be distinguished. This approach was proved to be a simple and effective means for identifying sugars. The collisional activation moss spectra of these characteristic ions are also discussed.