A New Zn(Ⅱ) Coordination Polymer Constructed by 1,4-Benzenedithiolate Dianion: [Zn(SC_6H_4S)(1,3-DPA)]_n

作     者：YAO Hua-Gang ZHANG Jun-Jun CAI Zhang-Wei ZHANG Chen-Yang YOU Li-Jun ZHENG Shuang 

作者机构：School of Chemistry and Chemical Engineering Guangdong Pharmaceutical University 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2015年第34卷第6期

页      面：911-916页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：Supported by the National Natural Science Foundation of China(No.21301035) 

主　　题：Zn(Ⅱ ) coordination polymer crystal structure 1,4-benzenedithioi zigzag chain 

摘      要：A new one-dimensional polymer, [Zn（SC6H4S）（1,3-DPA）]n （1, SC6H4S = 1,4-ben- zenedithiolate and 1,3-DPA = 1,3-diaminepropane）, has been synthesized and characterized by elemental analysis, PXRD, IR spectra, and single-crystal X-ray diffraction. The complex crystallizes in triclinic system, space group P1, with a = 6.7119（1）, b = 9.0230（2）, c = 10.4943（2） A, a = 69.288（1）, β = 75.848（1）, ）, = 81.513（1）°, V= 575.123（19） A3, Dc = 1.615 g/cm^3, Z = 2, F（000） = 288; the final S = 1.070, R = 0.0234, and wR = 0.0551. The compound consists of an infinite zigzag chain formed by [Zn（1,3-DPA）]^2＋ units joined by SC6H4S ligands. Each chain interacts with neighboring chains via weak N-H…S hydrogen bonds to form an extended three-dimensional （3D） supramolecular network. The thermal and photoluminescent properties of 1 have also been investigated.