POLYMERIZATION MECHANISM OF DIENES WITH HOMOGENEOUS RARE EARTH CATALYSTS

作     者：金鹰泰 张喜田 裴奉奎 吴越 

作者机构：Changchun Institute of Applied Chemistry Academia Sinica Changchun 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：1990年第8卷第2期

页      面：121-126页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：The Project is supported by "Laboratory of Physics & Chemistry  Academia Sinica" and "National Natural Science Foundation of China" 

主　　题：Reaction mechanism Diene coordination polymerization Homogeneous rare earth catalyst η~4-diene, η~3-allyl. 

摘      要：The reaction mechanisms of diene polymerization with homogeneous rare earth catalyst are studied by means of the spectra of ~1H-NMR, one-and two-dimensions ^(13)C-NMR. Based on the data of above NMR spectra, it is proposed that the polymerization reaction proceeds according to the following mechanism: η~4-diene (cis-trans-)and η~3-allyl (syn-anti-).