N-Doped porous carbon supported palladium nanoparticles as a highly efficient and recyclable catalyst for the Suzuki coupling reaction

作     者：Li Zhang Wen-Huan Dong Ning-Zhao Shang Cheng Feng Shu-Tao Gao Chun Wang 

作者机构：College of Science Agricultural University of Hebei 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2016年第27卷第1期

页      面：149-154页

核心收录：

学科分类：081704[工学-应用化学] 081705[工学-工业催化] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：financially supported by the National Natural Science Foundation of China (Nos. 31171698, 31471643) the Innovation Research Program of Department of Education of Hebei for Hebei Provincial Universities (No. LJRC009) Natural Science Foundation of Hebei Province (No. B2015204003) the Natural Science Foundation of Agricultural University of Hebei (Nos. LG201404, ZD201506) 

主　　题：Suzuki-Miyaura coupling reaction Pd catalyst N-Doped nanoporous carbon Metal-organic frameworks 

摘      要：A new catalyst, Pd particles supported on the N-doped porous carbon（PC） derived from Zn-based metal-organic frameworks（zeolitic imidazolate framework： ZIF-8）, was successfully prepared for the first *** as-prepared catalyst was designated as N-doped PC-Pd, and characterized by X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, scanning electron microscope, N_2 adsorption and inductively coupled plasma atomic emission spectroscopy. The N-doped PC-Pd composite exhibited high catalytic activity toward the Suzuki-Miyaura cross-coupling reactions. The yields of the products were in the range of 90%-99%. The catalyst could be readily recycled and reused at least 6 consecutive cycles without a significant loss of its catalytic activity.