Synthesis of Silsesquioxane Cages from Phenyl-cis-tetrol, 1,3-Divinyltetraethoxydisiloxane and Cyclopentyl Resins

作     者：Alan R. Bassindale Peter G. Taylor 

作者机构：Department of Chemistry Open UniversityDepartment of Chemistry Open University Walton Hall Milton Keynes MK7 6AA UKWalton Hall Milton Keynes MK7 6AA UK 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2004年第20卷第4期

页      面：433-436页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：Synthesis Silsesquioxane cage Phenyl-cis-tetrol 1,3-Divinyltetraethoxydisiloxane Cyclopentyl T resin 

摘      要：The synthesis of T_8, T_ 10 and T_ 12 silsesquioxane cages from a range of starting materials: phenyl-cis-tetrol, 1,3-divinyltetraethoxydisiloxane and cyclopentyl T resins by using tetra n-butylammonium fluoride(TBAF) as the catalyst is described in this paper. The reaction yields obtained viathe current route are better compared to those viathe literature routes. Some of the cage compounds have been characterized by X-ray crystallography.