THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID

作     者：万梅香 李明 米辛 姜谦 叶佩弦 

作者机构：Institute of Chemistry Academia Sinica Beijing 100080 Institute of Physics Academia Sinica Beijing 100080 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：1996年第14卷第1期

页      面：80-85页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 0817[工学-化学工程与技术] 08[工学] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：This work was partly supported by NNSFC Chinese Academy of Sciences and Director Foundation of the Institute of Chemistry Academia Sinica 

主　　题：polyaniline pernigraniline degenerated four waves mixing (DFWM) third-order nonlinear optical properties 

摘      要：The fully oxidized state of polyaniline (PANI), pernigraniline (PN), was synthesized by oxidation of the emeraldine base form of PAM dissolved in NMP solvent with m-chloroperoxybenzoic acid. The resulted PN was characterized by FTIR and UV-Visible spectra. The third-order nonlinear optical properties of PN in concentrated sulfuric acid (PN/H2SO4) were measured by a degenerated four wave mixing (DFWM) method. The results obtained suggest that the soliton-pair intermediate state associated with the degenerated state does not play a major role in the third order nonlinear optical properties of PANI.