Study on the Tin (IV) Complex of 4,5-benzo-1,2-dithiole-3-thione with IR, Analysis Centesimal, and Theatrically
Study on the Tin (IV) Complex of 4,5-benzo-1,2-dithiole-3-thione with IR, Analysis Centesimal, and Theatrically作者机构:Department of Chemistry Faculty of Sciences University Mentouri Constantine 25000 Algeria Department of Biology and Ecology Faculty of Nature and Life University Mentouri Constantine 25000 Algeria
出 版 物:《Journal of Chemistry and Chemical Engineering》 (化学与化工(英文版))
年 卷 期:2011年第5卷第9期
页 面:818-823页
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070302[理学-分析化学] 070303[理学-有机化学] 0703[理学-化学]
主 题:Tin (IV) complex 1 2-dithiole-3-thione theoretical study.
摘 要:A tin (IV) complex with 4,5-benzo-1,2-dithiol-3-thione (C7H4S3) (A), [SnCI4 (C7H4S3)2] (B) was synthesized. The structure of the obtained complex (B) was characterized by Infrared Spectroscopy (IR), analysis centesimal composition, and theoretical study. The complex (B) has an octahedral structure, where a tin in the center takes an octahedral geometry and is coordinated by four atoms of chlorine and two thiocarbonyl sulfur atom (C=S) of the ligand.