STRUCTURE AND GROWTH PHENOMENA OF C_(60) AND C_(70) SINGLE CRYSTALS
STRUCTURE AND GROWTH PHENOMENA OF C_(60) AND C_(70) SINGLE CRYSTALS作者机构:1. Institute of Metallurgy Physicochemistry and Materials Central South University of Technology 410083 Changsha China2. Department of Industrial Chemistry Mineralogical Institute University of Tokyo 113 Tokyo Japan
出 版 物:《Journal of Central South University》 (中南大学学报(英文版))
年 卷 期:1994年第6卷第1期
页 面:3-7页
学科分类:07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 0702[理学-物理学]
主 题:C_(60) C_(70) single crystals morphology
摘 要:C_(60) and C_(70) single crystals free from solvent contamination grew from their vapour. Large C_(60) crystals up to a size of about 5 mm × 3 mm × 3 mm and C_(70) crystals about 1 mm × 1 mm × 1 mm were obtained. C_(60) crystals with fee structure showed two types of morphological faces, namely {111} and {100 },frequently with twinning on {111} face. C_(70) crystals obtained have a hop structure with a = 10. 1 andc=16. 7 DSC and X-ray diffraction analysis indicated that C(70) crystal underwent phase transition below 100 ℃ Morphological observation suggests that the growth of C(60) and C(70) single crystals is based on layer spreading mechanism.