Liquid-phase epitaxy of metal organic framework thin films

作     者：FISCHER Roland A. 

作者机构：Organometallics and Materials ChemistryRuhr-Universitt Bochum 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2011年第54卷第12期

页      面：1851-1866页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：the European Union for funding the research projects on MOF thin films (Priority Program 1362 of the DFG) SUR-MOFs(6th FP, NMP4-CT-2006-032109) 

主　　题：coordination chemistry metal-organic frameworks (MOFs) liquid phase epitaxy step-by-step approach surface science thin film 

摘      要：Metal-organic framework(MOF) thin films are multilayer materials ranging from nanometers to micrometers in thickness,physically or chemically adhesive to a(functionalized) substrate and,in an ideal case,exhibiting low roughness and high *** innovative approaches have been developed for MOF thin film *** these advanced materials,surface-attached metal-organic frameworks(SURMOFs) are an important class of MOF ***,fabricated in a step-by-step liquid phase epitaxial(LPE) fashion by alternating deposition of metal and organic linker precursors on a functionalized substrate,for example,thiolate-based self-assembled monolayers(SAMs),have already exhibited their utility in both research and potential *** combine surface science and the chemistry of MOFs,possessing the following unique advantages that cannot be accessed through other methods:(i) precisely controlling thickness,roughness and homogeneity as well as growth orientation,(ii) studying of MOF growth mechanism,(iii) modifying/tailoring MOFs structures during the SURMOF growth and thus creating customizable properties,and(iv) existing in the form of thin film/membrane for direct applications,for example,as *** review discusses the oriented and crystalline SURMOFs fabricated by LPE approach,covering their preparation,growth mechanism,and characterization methodology as well as applications based upon the most newly updated knowledge.