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Synthesis of a Novel Aromatic Diamino-bridged Bis(β-cyclodextrin) and its Inclusion Complexation with Dyes Molecules

Synthesis of a Novel Aromatic Diamino-bridged Bis(β-cyclodextrin) and its Inclusion Complexation with Dyes Molecules

作     者:Yah ZHAO Xiao Qing LIU Hong You ZHU Zi Ming YANG Rong HUANG 

作者机构:College of Chemistry and Chemical Engineering Yunnan Normal University Kunming 650092 School of Chemical Science and Technology Yunnan University Kunming 650091 Experimental Center Yunnan University Kunming 650091 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:2006年第17卷第12期

页      面:1543-1546页

核心收录:

学科分类:081702[工学-化学工艺] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 

基  金:supported by the Yunnan Province Natural Science Foundation (Nos. 2003C009M and 2003B0014Q) 

主  题:Bridged bis(β-cyclodextrin)s cooperative binding inclusion complexation dye. 

摘      要:A novel brideed bis(β-cvclodextrin), 4, 4'-diaminodiphenyl ether-bfiged-bis (6-aimino-6-deoxv-β-cyclodextrin) 3, has been synthesized and its inclusion complexation behavior with three linear'guest dyes (AR, NR and MB ) has been investigated by. means of fluorescence spectrometry. The-result obtained demonstrated that the novel bridged bis(β-cyclodextnn) showed much higher affinities towards guest dyes than native β-cyclodextrin.

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