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Robust CoAl Alloy: Highly Active, Reusable and Green Catalyst in the Hydrogenolysis of Glycerol

Robust CoAl Alloy: Highly Active, Reusable and Green Catalyst in the Hydrogenolysis of Glycerol

作     者:郭晓洋 尹安远 郭晓东 郭秀英 戴维林 范康年 

作者机构:Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan University Shanghai 200433 China State Key Laboratory of High Field Laser Physics Shanghai Institute of Optics and Fine Mechanics Chinese Academy of Sciences Shanghai 201800 China 

出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))

年 卷 期:2011年第29卷第8期

页      面:1563-1566页

核心收录:

学科分类:081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 082503[工学-航空宇航制造工程] 0825[工学-航空宇航科学与技术] 

基  金:Project supported by the Major State Basic Resource Development Program (No. 2003CB 615807)  the National Natural Science Foundation of China (No. 20973042)  the Research Fund for the Doctoral Program of Higher Education (No. 20090071110011) and the Science & Technology Commission of Shanghai Municipality (No. 08DZ2270500) 

主  题:CoAl biomass glycerol hydrogenolysis 1,2-propanediol 

摘      要:CoAl alloy catalyst is found, for the first time, to be highly active, selective and reusable for the synthesis of diols via the hydrogenolysis of glycerol under mild conditions. The products and the catalyst could be self-separated from the reaction system through a simple reactor.

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