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Theoretical Studies on the Relationship Between the Structure and Property of Cellulose and Nitrocellulose——Nitration Activity and Mechanism

Theoretical Studies on the Relationship Between the Structure and Property of Cellulose and Nitrocellulose--Nitration Activity and Mechanism

作     者:Xiao Heming , Fan Jianfen and Li Yongfu (Department of Chemistry, East China Institute of Technology, Nanjing)Yu Hengtai (Institute of Theoretical Chemistry, Jilin University,Changchun) 

出 版 物:《Chemical Research in Chinese Universities》 (高等学校化学研究(英文版))

年 卷 期:1990年第6卷第2期

页      面:155-159页

核心收录:

学科分类:07[理学] 0703[理学-化学] 

主  题:Cellulose Nitrocellulose Nitration Activity Nitration Mechanism. 

摘      要:Many derivatives of industrially useful cellulose have hydroxyls of the anhydroglucose(AHG) units uncompletely substituted. Since each AHG unit of a cellulose molecule is a trihydric alcohol,consisted of one primary(position 6) and two secondary hydroxyl groups(positions 2 and 3), the distribution of substituents in these trihydric alcohol units could be different for different derivatives. The

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