An Efficient Synthetic Method of 11,12-Dihydroxyl Eudesmanolide Sesquiterpenoid from a -Santonin

作     者：Wu Jiong XIA De Run LI Yong Qiang TU Ao Cheng CAO 

作者机构：Department of ChemistryNational Laboratory of Applied Organic ChemistryLanzhou UniversityLanzhou 730000 Institute of Plant ProtectionChinese Academy of Agricultural SciencesBeijing 100094 

出 版 物：《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期：2001年第12卷第1期

页      面：21-24页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：We are grateful for financial support from the National Natural Science Foundation of China (NO.29972019) Educational Council Foundation (No.99208) Excellent Young Teacher Foundation 

主　　题：Introduction tertiary hydroxyl rearrangement-oxidation 

摘      要：A short and efficient procedure for introduction of tertiary hydroxyl to C-11 of eudesmanolide based on the rearrangement-oxidation of the exocylic double bond has been developed, which is synthetically valuable for a series of natural eudesmanolide sesquiterpenoids containing the 11,12-diol.