Recent advances in electrocatalytic conversion of nitrates into high-value products

作     者：Yuhao Qian Jiabao Lv Xuting Liu Zhifu Qi Angjian Wu 

作者机构：State Key Laboratory of Clean Energy UtilizationZhejiang UniversityHangzhou 30027ZhejiangChina Baima Lake Laboratory.Hangzhou 310053ZhejiangChina 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2024年第99卷第12期

页      面：50-65页

核心收录：

学科分类：081702[工学-化学工艺] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：the support from Key R&D Program of Zhejiang(2024SSYS0064) the Fundamental Research Funds for the Central Universities (2022ZFJH04) 

主　　题：Nitrate reduction reaction Electrocatalysis Ammonia synthesis C–N coupling 

摘      要：The electrocatalytic nitrate reduction reaction (NO_(3)RR) powered by renewable energy offers a promising approach for simultaneously reutilization of nitrate and synthesizing high-value ***,theoretical understanding of reaction mechanism was relative illusive,which is indispensable to rationally design of efficient ***,tuning the reaction microenvironment along with the scale-up device development is essential to promote the industrial deployment of electrocatalytic nitrate conversion,while relative research was *** this regard,recent advances in ammonia synthesis are firstly summarized,including the identification of active sites,exploration of the underlying reaction mechanisms,electrolyzer design and technical-economic ***,electrocatalytic C–N coupling based on NO_(3)RR to produce higher-value products such as urea and amino acids are also reviewed,to extend the application potential and economic ***,we highlight the existing challenges and the demand of future research for NO_(3)*** review anticipates to provide insights into synthesis of high-value products via NO_(3)RR,bridging the gap from laboratory research to industrial fabrication.