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SOLVENTLESS CYCLOCONDENSATIONS BETWEEN 1-NAPHTHOL AND BENZILS

SOLVENTLESS CYCLOCONDENSATIONS BETWEEN 1-NAPHTHOL AND BENZILS

作     者:Ji Ben MENG Zhong WEN Yong Mei WANG Hong Gen WANG Department of Chemistry and Central Laboratory,Nankai University,Tianjin,300071 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:1993年第4卷第10期

页      面:861-864页

核心收录:

学科分类:07[理学] 0703[理学-化学] 

主  题:IR SOLVENTLESS CYCLOCONDENSATIONS BETWEEN 1-NAPHTHOL AND BENZILS KBr NF 

摘      要:In the absence of organic solvents,the Lewis acid catalyzed cyclocondensation reactions between 1-naphthol and benzils gave 3-aryl-3-aryl naphtho[1,2-b]furan-2(3H)-ones(NFs) in good yields(62%~70%)An electrophilic substitution mechanism involving formation of n-EPD/v- EPA complexes and rearrangement of aryl group was proposed.

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