Non-isothermal decomposition kinetics and lifetime of Tb2(0-MBA)6(PHEN)2

作     者：ZHANGJianjun BAIJihai WANGRuifen WANGShuping LIJibiao ZHANG Jianjun BAIJihai WANG Ruifen WANG Shuping, and LI Jibiao1) Experimental Center, Hebei Normal University, Shijiazhuang 050016, China2) Department of Computer, Hebei Normal College of Science and Technology, Changli 066600, China3) Department of Chemistry, Hebei Normal University, Shijiazhuang 050091, China

作者机构：ExperimentalCenterNormalUniversityShijiazhuang050016China DepartmentofComputerHebeiNormalCollegeofScienceandTechnologyChangli066600China DepartmentofChemistryHebeiNormalUniversityShijiazhuang050091China 

出 版 物：《Rare Metals》 (稀有金属（英文版）)

年 卷 期：2003年第22卷第3期

页      面：155-159页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：This project was financially supported by the Natural Science Foundation of Hebei Province (Nos. 202140 and 203148) Hebei Education Department (No. 2001121) 

主　　题：thermochimica non-isothermal kinetics TG-DTG terbium complex O-methylbenzoate 1,10-phenanthroline 

摘      要：The thermal decomposition of Tb_2(O-MBA)_6(PHEN)_2 (O-MBA: o-methylbenzoate;PHEN: 1,10-phenanthroline) and its kinetics were studied under the non-isothermal condition bythermogravimetry-derivative thermogravimetry (TG-DTG) techniques. Kinetic parameters were obtainedfrom analysis of TG-DTG curves by the Achar method and the Madhusudanan-Krishnan-Ninan (MKN) *** most probable mechanism function was suggested by comparing the kinetic parameters. The kineticequation for the first stage can be expressed as dα/dt = Aexp(-E/RT)·3(1 - α)^(2/3). Thelifetime equation at mass loss of 10% was deduced as lnτ= -28.7429 + 19797.795/T by isothermalthermogravimetric analysis.