Studies on the Interaction of 12-Tungstophosphoric Acid and Diethylene Glycol

作     者：ZHAO Yu-sheng, HUA Shi-ying , WU Tong-hao and WEI Quan (Department of Chemistry, Jilin University, Changchun, 130023) Worked in Institute of Theoretical Chemistry, Jilin University, Changchun. 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：1993年第9卷第4期

页      面：317-323页

核心收录：

学科分类：07[理学] 0703[理学-化学] 

基　　金：Supported by the National Natural Science Foundation of China 

主　　题：IR NMR Diethylene glycol Proton oxonium ions 

摘      要：The homogeneous system of 12-tungstophosphoric acid and diethylene glycol was studied using IR and NMR spectra. It was found that the protons in 12-tungstophosphoric acid formed proton oxonium ions with the hydroxyl oxygen in diethylene glycol by hydrogen-bonds, and the formed proton oxonium ions could react with the terminal oxygens of heteropoly anions. The dehydration-cyclization mechanism of diethylene glycol in the presence of heteropoly acid was also proposed.