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Dipiphosphinoazines-from Rich Coordination Variability to Catalysis

Dipiphosphinoazines-from Rich Coordination Variability to Catalysis

作     者:J.ermák J.Storch M.Pota P.Vojtíek J.Sykora 

作者机构:Institute of Chemical Process Fundamentals AS CRv.v.i.Rozvojová 135 16502 PragueCzech Republic Department of Inorganic ChemistryCharles UniversityHlavova 2030 12840 PragueCzech Republic 

出 版 物:《复旦学报(自然科学版)》 (Journal of Fudan University:Natural Science)

年 卷 期:2007年第46卷第5期

页      面:599-页

核心收录:

学科分类:081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

主  题:diphosphinoazines transition metal complexes catalysis 

摘      要:1 Results Diphosphinoazines are very versatile,potentially up to tetradentate ligands,known to form complexes with many transition ***,we developed synthesis of diphosphinoazines with various substituents on phosphorus donor *** fine tuning allowed to design novel catalytic systems for several organic *** of Michael-type substrates with selected primary and secondary amines revealed the reactivity of some amines in non-catalyzed *** of methyl m...

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