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Skeletal Editing of Cyclic Molecules Using Nitrenes

作     者:Yi-An Xu Shao-Hua Xiang Jin-Teng Che Yong-Bin Wang Bin Tan 

作者机构:Shenzhen Grubbs InstituteDepartment of ChemistrySouthern University of Science and TechnologyShenzhenGuangdong518055 China 

出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))

年 卷 期:2024年第42卷第21期

页      面:2656-2667页

核心收录:

学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基  金:financial support from the National Key R&D Programof China(2022YFA1503703toB.T.and 2021YFF0701604 to B.T.) National Natural Science Foundation of China(22231004 to B.T.,22371113 to Y.-B.W.,22271135 to S.-H.X.) Guangdong Innovative Program(2019BT02Y335 to B.T.) Shenzhen Science and Technology Program(JCYJ20220818100604009 to Y.-B.W.,JCYJ20210324105005015 to S.-H.X.,JCYJ20210324104212035 to Y.-B.W.and KQTD20210811090112004 to B.T.) 

主  题:Nitrenes Skeletal Editing Cyclic Compounds Atom exchange Late-stage modification 

摘      要:Nitrenes,as neutral monovalent nitrogen-centered molecular species,can insert into various bond or remove nitrogen atoms from *** assisted single-atom skeletal editing,discovered decades ago,provides an efficient approach for the precise alteration of cyclic *** this review,we briefly summarize early studies on skeletal editing of cyclic frameworks involving nitrene species,and introduce several recent important advances systematically.

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