Templates for the synthesis of zeolites
作者机构:College of Chemical and Biological EngineeringZhejiang UniversityHangzhou310027China Kente Catalysts Inc.Fengxi West RoadModern Industrial ClusterXianju CountyZhejiang317300China Key Laboratory of Applied Chemistry of Zhejiang ProvinceDepartment of ChemistryZhejiang UniversityHangzhou310007China
出 版 物:《Chinese Journal of Structural Chemistry》 (结构化学(英文))
年 卷 期:2024年第43卷第4期
页 面:48-58页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
基 金:supported by National Key Research and Development Program of China(2022YFA1503602) Key Research and Development Program of Zhejiang Province(2021C01080) National Natural Science Foundation of China(22125204)
主 题:Zeolites Templates Zeolite synthesis Zeolite structure
摘 要:Though zeolites have been successfully synthesized for several decades,the roles of templates for zeolite synthesis are still not fully understood ***,many types of templates have been employed such as inorganic alkali metal ions,organic quaternary ammonium cations,organic amines,organic quaternary phosphonium cations,metal complexes and zeolite seeds,and the roles are mainly summarized into three aspects:structure-directing,space-filling and *** order to synthesize zeolites efficiently,the proposed principles to guide zeolite synthesis are the stabilization of energy between templates and zeolite framework,charge density mis-matching(CDM)and structure matching between zeolite frameworks and *** purpose of this review is to briefly summarize the progresses in recent years,clearly showing the roles of the templates for zeolite synthesis.