CO_(2)/NO_(x)-involved Electrochemical C-N Coupling Reactions

作     者：SUI Xiqing WU Limin JIA Shunhan JIN Xiangyuan SUN Xiaofu HAN Buxing 

作者机构：Beijing National Laboratory for Molecular SciencesKey Laboratory of Colloid and Interface and ThermodynamicsCenter for Carbon Neutral ChemistryInstitute of ChemistryChinese Academy of SciencesBeijing100190P.R.China School of Chemical SciencesUniversity of Chinese Academy of SciencesBeijing100049P.R.China Shanghai Key Laboratory of Green Chemistry and Chemical ProcessesSchool of Chemistry and Molecular EngineeringEast China Normal UniversityShanghai200062P.R.China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2024年第40卷第5期

页      面：764-775页

核心收录：

学科分类：081704[工学-应用化学] 08[工学] 0817[工学-化学工程与技术] 

基　　金：supported by the National Natural Science Foundation of China(Nos.22293015,22121002) the Beijing Natural Science Foundation,China(No.J210020) the Strategic Priority Research Program(A)of the Chinese Academy of Sciences(No.XDA0390400) the Project of the Photon Science Center for Carbon Neutrality of CAS 

主　　题：CO_(2)reduction NOx reduction C-N coupling Electrocatalysis 

摘      要：With the excessive use of fossil fuels leading to significant CO_(2)emissions,and the continuous increase of NOx in water bodies and soils,the use of electrochemical methods for the conversion of CO_(2)and NOx has garnered widespread attention as a green chemical approach due to its advantages of being environmentally friendly,low-carbon,and straightforward.C—N bonds are widely present in many value-added chemicals,such as urea,amides,and ***,traditional methods for constructing C—N bonds typically involve thermochemical ***,using electrochemical methods to catalyze the reduction of CO_(2)and NOx for C—N bond formation has emerged as a green and sustainable *** paper summarizes the research progress of electrochemical C—N bond construction involving CO_(2)and NOx from the perspectives of reaction mechanisms and catalytic system construction,reviews the electrochemical synthesis of urea,amines,amides,and oximes through electrochemical C—N bond construction,and finally analyzes the current problems and challenges in the field,providing prospects for its future development.