Recent advances in FeCl_(3)-photocatalyzed organic reactions via hydrogen-atom transfer

作     者：Xiao-Ya Yuan Cong-Cong Wang Bing Yu Xiao-Ya Yuan;Cong-Cong Wang;Bing Yu

作者机构：Green Catalysis CenterCollege of ChemistryZhengzhou UniversityZhengzhou 450001China National Engineering Research Center of Low-Carbon Processing and Utilization of Forest BiomassNanjing Forestry UniversityNanjing 210037China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2024年第35卷第9期

页      面：32-40页

核心收录：

学科分类：081704[工学-应用化学] 081705[工学-工业催化] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：the National Natural Science Foundation of China(Nos.21971224,22171249) Program for Science&Technology Innovation Talents in Universities of Henan Province(No.23HASTIT003) 

主　　题：FeCl_(3) Photocatalysis Ligand-to-metal charge transfer Hydrogen atom transfer Chlorine radical 

摘      要：In recent years,FeCl_(3)-photocatalyzed direct C–H/Si–H bond functionalization reactions have attracted huge *** those transformations,chlorine radical(Cl·)could be generated from FeCl_(3)via a ligandto-metal charge transfer(LMCT)/homolysis process under light *** resulting chlorine radical subsequently acts as a hydrogen atom transfer(HAT)agent to abstract the hydrogen atom of aliphatic C–H,O–H,or Si–H bonds to give the corresponding C/Si/O-centered radicals for various organic *** this review,we summarized the recent advances in the application of FeCl_(3)as a HAT photocatalyst for the C/Si–H functionalization to construct C–C,C–N,C–Si,C–S,C–B,and C-P bonds.