Emergent Physics in Metal−Organic Frameworks

作     者：Shaoze Wang Yingchao Wang Haozhou Sun Lei Sun 

作者机构：Department of ChemistrySchool of Science and Research Center for Industries of the FutureWestlake University600 Dunyu RoadHangzhouZhejiang 310030China Key Laboratoryfor Quantum Materials of Zhejiang ProvinceDepartment of PhysicsSchool of ScienceWestlakeUniversity600 DunyuRoadHangzhouZhejiang 310030China Institute of Natural SciencesWestlake InstituteforAdvanced Study18 Shilongshan RoadHangzhouZhejiang 310024China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2024年第42卷第20期

页      面：2514-2519页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：supports from the Zhejiang Provincial Natural Science Foundation of China(XHD23B0301) the Research Center for Industries of the Future(RCIF Project No.WU2023C006)at Westlake University.We thank Dr.Zhongyue Zhang and Dr.Shuigang Xu for helpful discussions 

主　　题：Metal-organic frameworks Emergent physics Strong correlations Superconductors Magnetic properties 

摘      要：Many-body interactions in condensed matter could lead to emergent phenomena spanning superconductivity,ferromagnetism,exciton condensation,*** emergence of these phenomena often requires highly ordered spatial arrangements of the interacting species to enforce specific space symmetries and interacting ***−organic frameworks(MOFs),crystalline materials formed by self-assembly of metal ions and organic ligands,allow for precise design of their crystal structures and sophisticated tuning of Coulombic interaction or magnetic coupling among lattice *** atomic-level designability combined with high crystallinity and versatile types of lattices(e.g.,kagome and honeycomb lattices)render MOFs as a great platform to investigate emergent *** this Emerging Topic,we summarize recent studies evidencing emergent phenomena in MOFs including strong correlations,superconductivity,charge density wave,long-range magnetic order,and quantum spin *** highlight the great potential of MOFs as quantum materials and discuss challenges including growth of high-quality single crystals and in-depth physical characterizations to reveal insights into the nature of physical properties of MOFs.