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Large reversible magnetocaloric effect in antiferromagnetic Er_(3)Si_(2)C_(2) compound

作     者:Hao Sun Lu Tian Xinqiang Gao Zhaojun Mo Jun Shen Baogen Shen Hao Sun;Lu Tian;Xinqiang Gao;Zhaojun Mo;Jun Shen;Baogen Shen

作者机构:School of Rare EarthsUniversity of Science and Technology of ChinaHefei230026China Ganjiang Innovation AcademyChinese Academy of SciencesGanzhou341000China Department of Energy and Power EngineeringSchool of Mechanical EngineeringBeijing Institute of TechnologyBeijing100081China 

出 版 物:《Journal of Rare Earths》 (稀土学报(英文版))

年 卷 期:2024年第42卷第8期

页      面:1555-1559,I0005页

核心收录:

学科分类:08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 

基  金:supported by the National Key Research and Development Program of China (2021YFB3501204) the National Science Foundation for Excellent Young Scholars (52222107) the National Science Foundation for Distinguished Young Scholars (51925605) the National Natural Science Foundation of China (52171195) Projects of Ganjiang Innovation Academy,Chinese Academy of Sciences (E055B002) 

主  题:Magnetic materials Magnetocaloric Metamagnetic transitions Magnetic phase transition Rare earths 

摘      要:The magnetic properties,magnetic phase transition and magnetocaloric effects(MCE) of Er_(3)Si_(2)C_(2) compound were investigated based on theoretical calculations and experimental *** on the first principles calculations,the antiferromagnetic(AFM) ground state type in Er_(3)Si_(2)C_(2) compound was predicted and its electronic structure was *** experimental results show that Ei_(3)Si_(2)C_(2) compound is an AFM compound with the Neel temperature(T_(N) of 7 K and undergoes a field-induced firstorder magnetic phase transition from AFM to ferromagnetic(FM) under magnetic fields exceeding 0.6 T at 2 *** magnetic transition process of Er_(3)Si_(2)C_(2) compound was investigated and *** values of the maximum magnetic entropy change(-ΔS_(M)^(max)) and the refrigeration capacity(RC) are 17 J/(kg·K)and 193 J/kg under changing magnetic fields of 0-5 T,*** a potential cryogenic magnetic refrigerant,the Er_(3)Si_(2)C_(2) compound also provides an interesting research medium to study the magnetic phase transition process.

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