Unlocking the power of ions toward enhanced electrocatalysis
作者机构：Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative MaterialsFudan University
出 版 物：《Science China Chemistry》 (中国科学:化学(英文版))
年 卷 期：2024年
核心收录：
学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术]
基 金：financially supported by the National Natural Science Foundation of China (22172036) the Shanghai Technology Innovation Program (Carbon-Neutral Program, 21DZ1207800)
摘 要：Electrocatalysis plays a vital role in advancing energy conversion and storage *** addition to the prominent strategies of advanced electrocatalysts,the exploration of the ion effects on electrocatalytic processes constitutes an emerging *** significant progress,challenges persist in understanding the controversial mechanisms and addressing the universality of these ion *** this feature article,we summarize our recent advances in exploring the ion effects on electrocatalytic oxidation reactions,mainly involving three systems:(1) hierarchical borate and fluoride anions synergize neutral water oxidation;(2) cation-intermediate interactions steer the glycerol oxidation selectivity;(3) cation coordination delays catechol polymerization and promotes selective ring C–C *** findings not only enrich our understanding of the ion effects through specific non-covalent interactions but also shed light on the potential of finely-tuned electrode–electrolyte interfaces toward the improved electrocatalytic performance for various electrocatalytic *** the summary,we outline the current challenges and opportunities within the ionic effect studies and offer insights into prospective research directions.
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