A widely used nonionic surfactant with desired functional groups as aqueous electrolyte additives for stabilizing Zn anode

作     者：Yue-Xian Song Xiao-Feng Wang Cai-Bin Liu Kai-Xuan Guo Xu-Huan Guo Xiao-Bin Zhong Yao-Hui Zhang Kai Wang Hui-Juan Guo Li-Xin Zhang Jun-Fei Liang Yue-Xian Song;Xiao-Feng Wang;Cai-Bin Liu;Kai-Xuan Guo;Xu-Huan Guo;Xiao-Bin Zhong;Yao-Hui Zhang;Kai Wang;Hui-Juan Guo;Li-Xin Zhang;Jun-Fei Liang

作者机构：School of Energy and Power EngineeringNorth University of ChinaTaiyuan 030051China Key Laboratory of Green Chemical Process of Ministry of EducationHubei Key Laboratory of Novel Chemical Reactor and Green Chemical TechnologySchool of Chemical Engineering and PharmacyWuhan Institute of TechnologyWuhan 430073China Shanxi Provincial Key Laboratory for High Performance Battery Materials and DevicesTaiyuan 030051China 

出 版 物：《Rare Metals》 (稀有金属（英文版）)

年 卷 期：2024年第43卷第8期

页      面：3692-3701页

核心收录：

学科分类：081702[工学-化学工艺] 0808[工学-电气工程] 081704[工学-应用化学] 0809[工学-电子科学与技术（可授工学、理学学位）] 0817[工学-化学工程与技术] 0806[工学-冶金工程] 08[工学] 0703[理学-化学] 

基　　金：financially supported by the National Natural Science Foundation of China (Nos.22102157 and U1910208) the Natural Science Foundation of Shanxi Province of China (Nos.20210302124097 and 20210302124663) the Opening Foundation of Shanxi Provincial Key Laboratory for HighPerformance Battery Materials and Devices (No.2022HPBMD02002) the Graduate Student Innovation Program of North University of China (No.20221871) the Natural Science Foundation of Hubei Province of China (No.2022CFB577) 

主　　题：Zn anode Dendrite growth Tween-20 polymer Surfactant additive Aqueous electrolyte 

摘      要：Aqueous Zn-ion batteries(AZIBs) have emerged as potential candidates for Li-ion batteries due to their intrinsic safety and high ***,metallic Zn anodes encounter dendrite growth and water-induced corrosion,rendering poor stability and severe irreversibility at the electrode/electrolyte interface during *** stabilize the Zn anode,we report a low-cost and effective nonionic surfactant,Tween-20 polymer,as an electrolyte additive for *** Tween-20,sequential oxyethylene groups tended to be preferentially adsorbed on the Zn electrode to form a shielding layer for regulating uniform Zn ***,the hydrophobic hendecyl chains prevented H_(2)O-induced corrosion on the Zn anode *** from the desired functional groups,when only trace amounts of Tween-20(0.050 g·L^(-1)) were used,the Zn anode displayed good cycling stability over 2170 h at10 mA·cm^(-2) and a high average Coulombic efficiency of98.94% over 1000 *** Tween-20 polymer can also be effectively employed in MnO_(2)/Zn full *** their toxicity,price and amount of usage,these surfactant additives provide a promising strategy for realizing the stability and reversibility of high-performance Zn anodes.