Recent Advances in Photochemical/Electrochemical Carboxylation of Olefins with CO_(2)

作     者：Qian Wang Yanwei Wang Min Liu Ganghui Chu Youai Qiu Qian Wang;Yanwei Wang;Min Liu;Ganghui Chu;Youai Qiu

作者机构：Xinjiang Laboratory of Native Medicinal and Edible Plant Resources ChemistryCollege of Chemistry and Environmental ScienceKashi UniversityKashiXinjiang 844000China state Key Laboratory and Institute of Elemento-Organic ChemistryFrontiers Science Centerfor New Organic MatterCollege of Chemistry Nankai University94 Weijin RoadTianjin 300071China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2024年第42卷第18期

页      面：2249-2266页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Financial support from National Key R&D Program of China(2022YFA1503200) National Natural Science Foundation of China(Grant Nos.22371149,22188101,22301144) the Fundamental Research Funds for the Central Universities(No.63223015) Frontiers Science Center for New Organic Matter,Nankai University(Grant No.63181206)and Nankai University is gratefully acknowledged 

主　　题：CO_(2) Carboxylation Olefins Photocatalysis Electrocatalysis Radical Reduction Difunctionalization 

摘      要：CO_(2) is an abundant,nontoxic,and renewable C1 feedstock in synthetic *** carboxylation of readily available olefins incorporating CO_(2) is regarded as a promising strategy to access high value-added carboxylic acids as well as CO_(2) ***,due to the thermodynamic stability and kinetic inertness of CO_(2) and the difficulty in controlling the regioselectivity,the carboxylation of olefins with CO_(2) still remains ***-type functionalization with olefins represented a powerful protocol and enabled the development of novel transformations in this *** recently,the advance of new technology,such as photoredox catalysis and the renaissance of electrochemistry in organic synthesis,offered access to unique chemical reactivities of radical precursors and provided new solutions to the functionalization of olefins.