Amine-functionalized metal organic framework@graphene oxide as filler in PAEK-containing carboxyl group membrane for ultrafiltration with ultra-high permeability and strong fouling resistance

作     者：Zhaoli Wang Wenjing Li Yi Zhang Yanyin Cheng Junjian Yu Tianming Dong Xiaoyu Chi Di Liu Zhe Wang Zhaoli Wang;Wenjing Li;Yi Zhang;Yanyin Cheng;Junjian Yu;Tianming Dong;Xiaoyu Chi;Di Liu;Zhe Wang

作者机构：School of Chemistry and Life ScienceChangchun University of TechnologyChangchun 130012China Advanced Institute of Materials ScienceChangchun University of TechnologyChangchun 130012China Key Laboratory of Advanced Functional Polymer Membrane Materials of Jilin ProvinceChangchun 130012China 

出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报（英文版）)

年 卷 期：2024年第70卷第6期

页      面：93-103页

核心收录：

学科分类：080706[工学-化工过程机械] 083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 08[工学] 0807[工学-动力工程及工程热物理] 

基　　金：support of this work by National Natural Science Foundation of China(22075031,51673030,51603017 and 51803011) Jilin Provincial Science&Technology Department(20220201105GX) Chang Bai Mountain Scholars Program of Jilin Province 

主　　题：Poly(arylene ether ketone)-containing Carboxyl groups(PAEK-COOH) UiO-66-NH_(2)@graphene oxide Hydrophilic modification Ultra-high selectivity Strong anti-fouling 

摘      要：Achieving high fouling resistance and permeability using membrane separation technology in water treatment processes remains a *** this work,a novel mixed-matrix membrane(MMM)(poly(arylene ether ketone)[PAEK]-containing carboxyl groups[PAEK-COOH]/UiO-66-NH_(2)@graphene oxide[GO])with superb fouling resistance and high permeability was prepared by the nonsolvent-induced phase separation method,by in-situ growth of UiO-66-NH_(2) on the GO layer,and by preparing hydrophilic *** the basis of the structure and performance analysis of the MMM,the maximum water flux reached 591.25 L·m^(-2)·h^(-1) for PAEK-COOH/UiO-66-NH_(2)@GO,whereas the retention rate for bovine serum albumin increased from 85.40%to 94.87%.As the loading gradually increased,the hydrophilicity of the MMMs increased,significantly enhancing their fouling *** strongest anti-fouling ability observed was 94.74%,which was 2.02 times greater than that of the pure *** the same time,the MMMs contained internal amide and hydrogen bonds during the preparation process,forming a cross-linked structure,which further enhanced the mechanical strength and chemical *** summary,the MMMs with high retention rate,strong permeability,and anti-fouling ability were successfully prepared.