Synthesis and characteristics of transparent Gd_(2)O_(3)ceramics with cubic structure
作者机构:World Lab Co.Nagoya456-8587Japan
出 版 物:《Journal of Advanced Ceramics》 (先进陶瓷(英文))
年 卷 期:2024年第13卷第4期
页 面:463-468页
核心收录:
学科分类:0809[工学-电子科学与技术(可授工学、理学学位)] 08[工学]
主 题:gadolinium oxide cubic hot isostatic press(HiP) diamagnetic Verdet constant
摘 要:Transparent Gd_(2)O_(3)ceramics with a cubic crystal structure were successfully synthesized for the first *** Gd_(2)O_(3)ceramics subjected to hot isostatic press(HIP)at 1070℃consisted of uniform grains of 2-3μm,and only a few residual pores could be detected inside the materials.X-ray diffraction(XRD)shows that the obtained polycrystalline materials have a cubic crystal structure,and the transmission polarized light observation shows that there is no birefringence inside the materials,indicating inherent optical properties of the cubic crystal *** optical absorption edge is 640 nm(optical band gap:2.1 eV),and the transmittance in the visible to near-infrared region is 72%,which is close to the theoretical transmittance calculated from Fresnel *** constant of this material is almost wavelength-independent,and it is diamagnetic since it has the opposite polarity to that of common paramagnetic materials.