High-efficiency PdNi single-atom alloy catalyst toward cross-coupling reaction

作     者：Baokang Geng Xiang Chu Li Liu Lingling Zhang Shuaishuai Zhang Xiao Wang Shuyan Song Hongjie Zhang Baokang Geng;Xiang Chu;Li Liu;Lingling Zhang;Shuaishuai Zhang;Xiao Wang;Shuyan Song;Hongjie Zhang

作者机构：State Key Laboratory of Rare Earth Resource UtilizationChangchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China School of Applied Chemistry and EngineeringUniversity of Science and Technology of ChinaHefei 230026China Department of ChemistryTsinghua UniversityBeijing 100084China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2024年第35卷第7期

页      面：480-483页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：supported by the financial aid from National Science and Technology Major Project of China(No.2021YFB3500700) National Natural Science Foundation of China(Nos.22020102003,22025506 and 22271274) Program of Science and Technology Development Plan of Jilin Province of China(Nos.20230101035JC and 20230101022JC) 

主　　题：Single-atom alloy Cross-coupling reaction Palladium catalysis Heterogeneous catalysis High-efficiency 

摘      要：The preparation of Pd-based catalysts with rich electrons and a high atom dispersion rate is of great significance for improving the reactivity of cross-coupling reactions,which is a powerful tool for pharmaceutical and fine chemical ***,we report a PdNi single-atom alloy(SAA)catalyst in which isolated Pd single atoms are anchored onto the surface of Ni nanoparticles(NPs)applied for Suzuki coupling reactions and Heck coupling *** 0.1%PdNi SAA exhibits extraordinary catalytic activity(reaction rate:17,032.25 mmol h^(-1)gPd^(-1))toward the Suzuki cross-coupling reaction between 4-bromoanisole and phenylboronic acid at 80℃for 1 *** excellent activity is supposed to attribute to the 100 percent utilization rate of Pd atoms and the highly stable surface zero-valance Pd atoms,which provides abundant sites and electrons for the adsorption and fracture of the C-X(X=Cl,Br,I)***,our work demonstrates the excellent application prospect of SAAs for cross-coupling reactions.