Tb(Ⅲ)functionalized MOF based self-calibrating sensor integrated with logic gate operation for efficient epinephrine detection in serum
作者机构:Shanxi Key Laboratory of Advanced Carbon Electrode MaterialsShanxi Coal Mine Water Treatment Technology Innovation CenterSchool of Chemistry and Chemical EngineeringNorth University of ChinaTaiyuan030051China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education)College of ChemistryNankai UniversityTianjin300071China
出 版 物:《Journal of Rare Earths》 (稀土学报(英文版))
年 卷 期:2024年第42卷第5期
页 面:987-994,I0006页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 1010[医学-医学技术(可授医学、理学学位)] 070302[理学-分析化学] 0703[理学-化学] 10[医学]
基 金:Project supported by the National Natural Science Foundation of China(21801230,21905255) Natural Science Foundation of Shanxi Province(202203021211090) Young Academic Leader Supported Program of North University of China(QX201904) Shanxi Key Laboratory of Advanced Carbon Electrode Materials(202104010910019) The Key Laboratory Research Foundation of North University of China
主 题:Metal-organic framework Post-synthetic modification Self-calibrating sensor Logic gate operation Epinephrine detection Rare earths
摘 要:By anchoring Tb^(3+)ions on its free carboxyl groups of the nanocaged NiMOF,a dual-emission self-calibrating sensor of Tb^(3+)@NiMOF was fabricated through coordination post-synthetic modification(PSM)*** Tb^(3+)ions as the secondary fluorescent signal and sensing active sites,Tb^(3+)@NiMOF presents great potentials in visually and efficiently monitoring EPI in serum,with high sensitivity and selectivity,fast response,excellent recyclable,and the low detection limit(LOD,3.06 ng/mL).Furthermore,a tandem combinational logic gate based intelligent detection system was constructed to improve the practicability and convenience of epinephrine(EPI)detection in serum by comparing the light emitted colour with the series standard colour cards preset in the *** work provides a promising approach of developing metal-organic frameworks(MOFs)based self-calibrating sensors for intelligent detection of bioactive molecules.