Design Principles and Mechanistic Understandings of Non-Noble-Metal Bifunctional Electrocatalysts for Zinc-Air Batteries

作     者：Yunnan Gao Ling Liu Yi Jiang Dexin Yu Xiaomei Zheng Jiayi Wang Jingwei Liu Dan Luo Yongguang Zhang Zhenjia Shi Xin Wang Ya‑Ping Deng Zhongwei Chen Yunnan Gao;Ling Liu;Yi Jiang;Dexin Yu;Xiaomei Zheng;Jiayi Wang;Jingwei Liu;Dan Luo;Yongguang Zhang;Zhenjia Shi;Xin Wang;Ya-Ping Deng;Zhongwei Chen

作者机构：Power Battery and Systems Research CenterState Key Laboratory of CatalysisDalian Institute of Chemical PhysicsDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023People’s Republic of China Department of Chemical EngineeringUniversity of WaterlooWaterlooON N2L 3G1Canada Institute of Carbon NeutralityZhejiang Wanli UniversityNingbo 315100People’s Republic of China College of Materials and ChemistryChina Jiliang UniversityHangzhou 310018People’s Republic of China 

出 版 物：《Nano-Micro Letters》 (纳微快报（英文版）)

年 卷 期：2024年第16卷第9期

页      面：13-48页

核心收录：

学科分类：0808[工学-电气工程] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：the Natural Science Foundation of China(Grant No:22309180) Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No:XDB0600000,XDB0600400) Liaoning Binhai Laboratory,(Grant No:LILBLB-2023-04) Dalian Revitalization Talents Program(Grant No:2022RG01) Youth Science and Technology Foundation of Dalian(Grant No:2023RQ015) the University of Waterloo 

主　　题：Zinc-air batteries Bifunctional electrocatalysts Design principles Mechanistic understandings 

摘      要：Zinc-air batteries(ZABs)are promising energy storage systems because of high theoretical energy density,safety,low cost,and abundance of ***,the slow multi-step reaction of oxygen and heavy reliance on noble-metal catalysts hinder the practical applications of ***,feasible and advanced non-noble-metal elec-trocatalysts for air cathodes need to be identified to promote the oxygen catalytic *** this review,we initially introduced the advancement of ZABs in the past two decades and provided an overview of key developments in this ***,we discussed the work-ing mechanism and the design of bifunctional electrocatalysts from the perspective of morphology design,crystal structure tuning,interface strategy,and atomic *** also included theoretical studies,machine learning,and advanced characterization technologies to provide a comprehensive understanding of the structure-performance relationship of electrocatalysts and the reaction pathways of the oxygen redox ***,we discussed the challenges and prospects related to designing advanced non-noble-metal bifunctional electrocatalysts for ZABs.