Crystalline porous materials for catalytic conversion of lignin-related substances

作     者：Qing Huang Pengfei Wu Xiu-Fen Li Yi-Rong Wang Dan Tian Ya-Qian Lan 

作者机构：College of Materials Science and EngineeringNanjing Forestry UniversityNanjingJiangsuP.R.China School of ChemistrySouth China Normal UniversityGuangzhouP.R.China Co-Innovation Center for Sustainable Forestry in Southern ChinaNanjing Forestry UniversityNanjingJiangsuP.R.China 

出 版 物：《Aggregate》 (聚集体（英文）)

年 卷 期：2024年第5卷第3期

页      面：142-163页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：National Natural Science Foundation of China,Grant/Award Numbers:22101089,22225109,22175094,21871141,21871142,22071109,92061101 Guangdong Basic and Applied Basic Research Foundation,Grant/Award Number:2020A1515110836 Open Fund of Energy and Materials Chemistry Joint Laboratory of SCNU and TINCI,Grant/Award Number:SCNU-TINCI-202204 

主　　题：catalytic conversion covalent organic frameworks lignin lignin derivatives lignin model compounds metal-organic frameworks 

摘      要：The conversion of the biomass into eco-friendly fuels and chemicals has been exten-sively recognized as the essential pathway to achieve the sustainable economy and carbon neutral ***,as a kind of promising biomass energy,has been certified to produce the high-valued chemicals and *** efforts have been made to develop various catalysts for lignin catalytic *** metal-organic frameworks(MOFs)and covalent organic frameworks(COFs)belong to very important heterogeneous porous catalysts due to their regular porous struc-tures,high specific surface area,and precisely tailored *** the review,thefirst part focused on the catalytic conversion of lignin,lignin model compounds,and lignin derivatives using the pristine MOFs,functional MOF composites,and MOF-derived *** second part summarized the catalytic conversion of lignin model compounds using pristine COFs and functional COF *** review here mainly concentrated on the design of the materials,screening of catalytic conditions,and explorations of the corresponded ***fically,(1)we summarized the MOF-and COF-based materials for the effects on the catalytic trans-formation of lignin-related substances;(2)we emphasized the catalytic mechanism of C–C and C–O bonds cleavage together with the structure–activity relationships;(3)we in-depth realized the relationship between the chemical/electronic/structural properties of the MOF-and COF-based catalysts and their catalytic performance for lignin-related ***,the challenges and future perspectives were also discussed on the catalytic conversion of lignin-related substances by MOF-and COF-based catalysts.