Review on inorganic and polymeric materials-coordinated metal-organic-framework photocatalysts for green hydrogen evolution

作     者：Dong-Eun Lee Mohtaram Danish Umair Alam Wan-Kuen Jo 

作者机构：School of ArchitectureCivilEnvironmental and Energy Engineering Kyungpook National University80 Daehak-roBuk-guDaegu 41566Republic of Korea School of Chemical EngineeringYeungnam UniversityGyeongsanGyeongbuk 38541Republic of Korea 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2024年第92卷第5期

页      面：322-356页

核心收录：

学科分类：0820[工学-石油与天然气工程] 081702[工学-化学工艺] 081704[工学-应用化学] 081705[工学-工业催化] 07[理学] 0817[工学-化学工程与技术] 08[工学] 070304[理学-物理化学(含∶化学物理)] 0703[理学-化学] 

基　　金：the financial support they received from the National Research Foundation of Korea(NRF)grants funded by the Korean government(MSIT)(NRF-2018R1A5A1025137 and 2023R1A2C1002599) 

主　　题：Renewable energy Environmental challenge Heterojunction Water splitting Photocatalysis 

摘      要：Metal-organic frameworks(MOFs)possess a distinct advantage over conventional heterogeneous photocatalysts because of their carefully defined architecture and particular pores,which facilitate the targeted incorporation of other efficient cocatalysts or semiconductor *** integration of MOFs with other materials has resulted in significant breakthroughs,as the coupled materials improve the performance due to the combined *** unique MOF structures allow them to host foreign materials,which results in harvesting the visible region of the solar spectrum and effectively mitigating charge recombination by promoting charge *** review presents an evaluation of the latest developments in the utilization of surface and/or pore chemistry of MOF-supported heterojunctions for photocatalytic green-hydrogen generation with a basic understanding of the mechanism *** review begins with the basic principles of photocatalysis,the significance of MOFs,their optical properties,the methods used for synthesizing MOFs,and their coordination with other inorganic and polymeric ***,methods to increase photocatalytic H2 evolution using MOF-supported heterojunction have been proposed as standard ***,to address environmental challenges,we highlight the future potential of MOF-supported heterojunctions for use in green-energy *** hope that this review provides guidance to researchers in the development of effective heterojunctions based on MOFs to address challenges in energy applications and catalytic processes.