Aggregation of titanium-oxo clusters

作     者：Yu-Long Xie Wei-Hui Fang Jian Zhang 

作者机构：State Key Laboratory of Structural ChemistryFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhouFujianPeople’s Republic of China University of Chinese Academy of SciencesChinese Academy of SciencesBeijingBeijingPeople’s Republic of China 

出 版 物：《Aggregate》 (聚集体（英文）)

年 卷 期：2024年第5卷第3期

页      面：107-126页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：National Natural Science Foundation of China,Grant/Award Numbers:U23A2095,22371278,92061104 Science Fund for Distinguished Young Scholars of Fujian Province,Grant/Award Number:2021J06035 Funding of Fujian Provincial Chemistry Discipline Alliance,Grant/Award Number:50025401 Youth Innovation Promotion Association of the Chinese Academy of Sciences,Grant/Award Number:Y2021081 

主　　题：cluster chemistry framework materials ligand engineering photocatalysis titanium-oxo clusters 

摘      要：Compared with nanoparticle-aspect relatives titanium dioxide(TiO2),titanium-oxo clusters(TOCs)are atomically structural-determined and can be further precisely modified through coordination and supramolecular *** parallel research direction is titanium-based metal-organic frameworks,and those based on TOC have attracted particular attention because of their high optical performances resulting from the cluster aggregation *** challenging,assembling macro-materials from specific clusters helps establish the assembly chemistry of clusters and incorporates porous andflexible characteristics into a single bulk *** separate reviews are reported in these two branches,no com-prehensive review is available to highlight the bridges between ***,we review and summarize the development and progress of new aggregation of TOCs,from intramolecular unique cluster aggregation to hierarchical intermolecular aggre-gation via covalent forces,coordination bonds,and non-covalent forces using the specific clusters as *** hope this reviewfills the gap in the methodology of assembling particular-aggregated TOCs and their derived frameworks,providing general guidance to researchers interested in this area.