Nano-flower spherical SnS2 combined with a special lithium storage mechanism as a multifunctional separator for lithium-sulfur batteries contributes to ultra-high initial discharge specific capacity

作     者：LIU HuaZhong XIONG YaPing HUANG MouZhi CHEN ZongMin YANG Xiao ZHANG Ze YANG ZhenYu CAI JianXin 

作者机构：School of Chemistry&Chemical EngineeringNanchang UniversityNanchang 330031China 

出 版 物：《Science China(Technological Sciences)》 (中国科学（技术科学英文版）)

年 卷 期：2024年第67卷第2期

页      面：509-519页

核心收录：

学科分类：0710[理学-生物学] 0808[工学-电气工程] 07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学] 

基　　金：supported by the National Natural Science Foundation of China(Grant Nos.51662029 and 21363015) 

主　　题：Li-S batteries modified separators polysulfides catalytic conversion high electrochemical activity 

摘      要：The critical factors that limit the electrochemical performance of lithium-sulfur(Li-S)batteries are mainly the“shuttle effectof polysulfides and the slow redox reaction between lithium polysulfides(LiPSs).Herein,a nano-sphere-type material selfassembled from tin disulfide nanosheets is designed and applied to the Li-S cell separator in this *** SnS_(2)@PP modified separator not only acts as a dual restriction for LiPSs by chemisorption and physical *** the same time,it improves the catalytic activity of the redox reaction between *** SnS_(2)has extremely high electrochemical ***,a portion of the lithium ions can be inserted into SnS_(2)to form Li_(x)SnS_(2)and contribute to the capacity during the first discharge of the *** addition,Li_(x)SnS_(2)possesses a high degree of stability,and it does not undergo further de-alloying reactions even at the high potential of the Li-S *** benefit is that the steady-state Li_(x)SnS_(2)acts as a lithium-containing *** can form special Li^(+)channels on the surface of the separator,thus greatly improving the efficiency of Li+*** results showed that the SnS_(2)@PP-based cell exhibited extremely high initial discharge specific capacity(1477 m Ah g^(-1)at 0.1 C)and excellent rate performance(631 m Ah g^(-1)at 5 C).Even after 1000 cycles at 2 C,the cell exhibited a low decay rate of 0.06%per cycle on *** addition,the superior electrochemical performance was obtained even with a high sulfur loading of 5.1 mg cm^(-2)and low electrolyte of E/S=8μL mg^(-1).